a, A 6.7-cm-long piece of burnt bone (Br-SE-Os) trapped between stalagmite elements in structure E (Extended Data Fig. 5) was almost completely covered by calcite except on its medullar side. Desmond Clark (1979:7) observed that without radiocarbon dating "we would still be foundering in a sea of imprecisions sometime bred of inspired guesswork but more often of imaginative speculation." And as Colin Renfrew (1973) aptly noted over 30 years ago, the "Radiocarbon Revolution" transformed how archaeologists could interpret the past and track cultural changes through a period in human history where we see among other things the massive migration of peoples settling virtually every major region of the world, the transition from hunting and gathering to more intensive forms of food production, and the rise of city-states.However, as with any dating technique there are limits to the kinds of things that can be satisfactorily dated, levels of precision and accuracy, age range constraints, and different levels of susceptibility to contamination.
Note that the burnt bone was covered by a reddish and blackened speleofact (Extended Data Fig. d, FTIR spectroscopy (blue spectrum on the black part of the bone, green spectrum on the grey part of the bone, red spectrum on the overlying calcite crust and grey spectrum on a modern char) show well-characterized PO.
In contrast to relative dating techniques whereby artifacts were simply designated as "older" or "younger" than other cultural remains based on the presence of fossils or stratigraphic position, 14C dating provided an easy and increasingly accessible way for archaeologists to construct chronologies of human behavior and examine temporal changes through time at a finer scale than what had previously been possible.
The application of Accelerator Mass Spectrometry (AMS) for radiocarbon dating in the late 1970s was also a major achievement.
Compared to conventional radiocarbon techniques such as Libby's solid carbon counting, the gas counting method popular in the mid-1950s, or liquid scintillation (LS) counting, AMS permitted the dating of much smaller sized samples with even greater precision.
Regardless of the particular 14C technique used, the value of this tool for archaeology has clearly been appreciated.